Hydroxyl-Directed Stereoselective Diboration of Alkenes
نویسندگان
چکیده
An alkoxide-catalyzed directed diboration of alkenyl alcohols is described. This reaction occurs in a stereoselective fashion and is demonstrated with cyclic and acyclic homoallylic and bishomoallylic alcohol substrates. After oxidation, the reaction generates 1,2-diols such that the process represents a method for the stereoselective directed dihydroxylation of alkenes.
منابع مشابه
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عنوان ژورنال:
دوره 136 شماره
صفحات -
تاریخ انتشار 2014